Chemistry - Ch 20 Flashcards

0
Q

Oxidizing agent (oxidant)

A

removes electrons from another substance by acquiring them itself

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1
Q

Electrochemistry

A

study of the relationships between electricity and chemical reactions

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2
Q

Reducing agent (reductant)

A

substance that gives up electrons, thereby causing another substance to be reduced

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3
Q

Half-reactions

A

equations that show either oxidation or reduction alone

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4
Q

Voltaic (galvanic) cell

A

device in which the transfer of electrons takes place through an external pathway rather than directly between reactants

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5
Q

anode

A

the electrode at which oxidation occurs

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6
Q

cathode

A

the electrode at which reduction occurs

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7
Q

Electromotive force (emf)

A

potential difference between the 2 electrons of a voltaic cel provides the driving force that pushes electrons through the external circuit

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8
Q

Cell potential

A

emf of a cell (Ecell)

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9
Q

Standard emf

A

standard cell potential

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10
Q

Standard Reduction Potentials

A

standard electrode potentials tabulated for reduction reactions

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11
Q

Standard hydrogen electrode (SHE)

A

electron designed to produce the reference half reaction (2H+ (aq, 1M) + 2e- –> H2 (gas, 1 atm)

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12
Q

faraday (F)

A

quantity of electrical charge on one mole of electrons

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13
Q

Nernst equation

A

equation that relates the cell emf, E, to the standard emf and the reaction quotient

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14
Q

Concentration cell

A

a cell based solely on the emf generated because of a difference in concentration

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15
Q

Battery

A

portable, self-contained electrochemical power source that consists of one or more voltaic cells

16
Q

Fuel cells

A

voltaic cells that perform conversion of electricity from conventional fuels (H2, CH4)

17
Q

Corrosion

A

spontaneous redox reactions in which a metal is attacked by some substance in its environment and converted to an unwanted compound

18
Q

Cathodic protection

A

protecting a metal from corrosion by making it the cathode in an electrochemical cell

19
Q

Electrolysis reactions

A

nonspontaneous redox reactions (driven by an outside source of electrical energy)

20
Q

Electrolytic cells

A

where electrolysis reactions take place

21
Q

Watt (w)

A

unit of electrical power (rate of energy expenditure)