Chemistry - Ch 17 Flashcards

0
Q

Buffered solutions (buffers)

A

solutions which contain a weak conjugate acid-base pair can resist drastic changes in pH upon the addition of small amounts of strong acid or strong base

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1
Q

Common-Ion Effect

A

observation that whenever a weak electrolyte and a strong electrolyte contain a common ion, the weak electrolyte ionizes less than it would if it were alone in solution

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2
Q

Henderson-Hasselbalch Equation

A

pH = pKa + log [base/acid]

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3
Q

Buffer capacity

A

amount of acid or base the buffer can neutralize before the pH begins to change to an appreciable degree

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4
Q

pH range

A

range over which a buffer acts effectively

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5
Q

pH Titration Curve

A

a graph of the pH as a function of the volume of the added titrant

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6
Q

Solubility-product constant (solubility product)

A

Ksp; equilibrium constant describing how soluble the solid is in water

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7
Q

Complex ion

A

an assembly of a metal ion and the Lewis bases bonded to it

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8
Q

Formation constant

A

Kf; for a metal ion complex, the equilibrium constant for formation of the complex from the metal ion and base species present in solution; it is a measure of the tendency of the complex to form

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9
Q

Amphoteric oxides and hydroxides

A

substances capable of behaving as either an acid or base

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10
Q

Qualitative analysis

A

determines only the presence of absence of a particular metal ion

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11
Q

Quantitative analysis

A

determines how much of a given substance is present

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