GLASS Flashcards

1
Q

what is the major component of glass?

A

silicon (silicon dioxide)

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2
Q

define glass

A

amorphous, inorganic product of fusion that has been cooled to a rigid condition without crystallizing

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3
Q

where can silicon be found?

A

as silica or silicate

  • quartz
  • sand
  • cristobalite
  • feldspar
  • kaolinite
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4
Q

geometric structure of a silica molecule?

A

tetrahedral

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5
Q

describe silica’s physical properties

A
  • high melting point
  • high toughness
  • low/null transparency
  • poor inertness
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6
Q

what is silica’s chemical formula?

A

SiO2

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7
Q

why can’t you fold glass?

A

chemical bonding

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8
Q

what does it mean to have an amorphous structure?

A

molecular units have disordered arrangement but sufficient cohesion to produce mechanical rigidty

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9
Q

how is an amorphous structure created?

A

introducing other elements like potassium, magnesium, sodium, calcium, etc

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10
Q

what is the basic formula of glass?

A
  • silica (SiO2)
  • limestone (CaO)
  • soda ash (Na2O)
  • alumina (Al2O3)
  • cullet (recycled glass)
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11
Q

network formers of glass

A

SiO2

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12
Q

network modifiers of glass

A

Na2CO3 –> Na2O + CO2

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13
Q

stabilizers in glass

A

CaCO3 –> CaO + CO2

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14
Q

what’s the point of using cullet?

A

reduces cost/energy

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15
Q

formers

A
  • silica sand
  • boron oxide
  • cullet
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16
Q

fluxes

A
  • sodium carbonate

- potassium carbonate

17
Q

stabilisers

A
  • calcium carbonate
  • magnesium carbonate
  • barium carbonate
18
Q

fining agent

A
  • sodium sulphate
19
Q

colourant, bleaching

A
  • metal oxides
20
Q

what colors can you turn glass?

A
  • amber (carbon & sulphur compounds)
  • blue (cobalt oxide)
  • green (ferrous sulfate, chromium oxide)
  • yellow (ferric oxide, antimony oxide)
  • blue-green (cobalt oxide, chromium oxide)
  • opal (calcium oxide)
21
Q

steps to glass production

A
  • raw materials
  • mixing
  • melting
  • forming
  • glass products
22
Q

how are metal impurities removed from the raw materials?

A

magnets

23
Q

80-90% of the heat flux is consumed at what step of glass production?

A

batch melting (melting and sand dissolution)

24
Q

what is primary fining?

A

step that removes metals

25
Q

what is secondary fining?

A

second removal of impurities

26
Q

temperature of batch input

A

25C

27
Q

temperature of batch melting

A

1200C

28
Q

temperature of sand grain dissolution

A

1400C

29
Q

temperature of fining

A

1500C

30
Q

temperature of fining

A

1500C

31
Q

temperature of refining and conditioning

A

1250C

32
Q

about ____ -____% of mass of normal soda-lime silica batches is transferred into volatile _____

A

14-20%; CO2

33
Q

fine cullet enables glass to foam at a (higher/lower) temperature and (longer/shorter) time than coarse cullet

A

lower, shorter

34
Q

how do you remove bubbles from glass?

A

fining of glass melt: use high temps and add Na2SO4 as a binding agent to generate new gases, making new bubbles. these will combine with the original bubbles and make it easier for them to ascend.

35
Q

larger bubbles take (longer/shorter) time to ascend

A

shorter